I'm not "in the know", but I just bought two big sheets of 1/4" acrylic from Regal Plastics, to use for my new sump.
It is seriously heavy stuff. I can't imagine needing anything thicker for the size you're talking about, especially if you have a frame around the top the way Marc does it.
I think it sort of depends on the structure of the inside of the sump, as far as cross-pieces and sections that add structural integrity to the whole thing. i.e., a big four-walled box might bow, but divide it into sections, and it becomes a lot stronger.