I have a 45 Gallon Reef with a 20 Gallon Sump with about 60lbs of live rock and I had just got done doing a 5 gallon water change and i meant to empty the skimmer collection cup before i turned the pumps back on but, i forgot to empty the cup I didn't notice until it was too late that the skimmer was skimming very very wet. It was about half full of a week old skimmate. By the time I caught it the water was almost clear in the collection cup. My question is. What can i expect? ammonia spike? nitrate spike? Both? And should i do another water change?