Yes it is possible. My own setup I have a redundant system, I have a JBJ ATO unit for my top-off with two sensors, one in the sump that turns on when the level goes down and one in the holding tank for the RO so it turns off when it gets too low. This prevents constant dosing and emptying of my RO into the system. I also have my controller set to turn off if pH hits 8.30 and that shuts off the ATO itself to prevent too much kalk. So far, I have had no issues with the pH going too high but have the security that if it does things will shut off. I also have it all run via LiterMeter pump so there is no chance of siphon issues.
You can do it, but you need to do it in a manner that builds in safety features. I don't know what kind of pump you are using for it, but I since you have a RK2, you have a pH probe correct? I would run the pump on your controller to prevent the pH from getting too high.
You could do this... have two plugs dedicated to the reactor and top-off. Run the kalk as your primary and have it set to turn off if pH gets to say 8.3 or 8.4 and then THAT even shuts off the reactor and activates the second plug that turns things over to your secondary top-off. That system may require two sensor setups in your sump, but will give you what you need.